If the current limit of concurrent users is reached, no additional users will be able to log in (not even users with high permissions). However, you can set up a user management account that can always log in and log users out if required.
A user management account only has permissions to log in and Log Out Users.
Follow these steps to set up a user management account:
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Go to Utilities > Users.
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From the Options side panel, click on New.
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Enter the details for the user. For the User Type, select 'User View Only'
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Click on 'Save'.